Publications

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2011
Liu, HJ, Chou JP, Li RW, Wei CM, Miki K.  2011.  Trimeric precursors in formation of Al magic clusters on a Si(111)-7 x 7 surface, Feb. Physical Review B. 83:6., Number 7 AbstractWebsite

The formation process of Al magic clusters on the Si(111)-7 x 7 surface was investigated by means of a variable-temperature scanning tunneling microscope (STM) in situ and was interpreted using density-functional theory (DFT) calculations. At a growth temperature of 450 degrees C, Al atoms hopped among the corner, center, and T4 sites and also across the dimer rows on the Si(111)-7 x 7 surface. At low coverage below 0.08 ML, a single Al atom was adsorbed on the corner or center site. When the coverage was increased to 0.08 ML, Al dimers and trimers appeared, and Al magic clusters were also observed. However, no Al tetramers or pentamers were experimentally confirmed. Careful analysis of STM images suggests that Al trimers could be key precursors for the formation of Al magic clusters, and DFT calculations verified this interpretation. Total-energy calculation results using DFT reveal that this is due to the small energy gain from Al trimer to Al tetramer. These results are important for understanding the atomic structure and the formation mechanism of the magic clusters on the Si(111)-7 x 7 surface.

Gruznev, DV, Matetskiy AV, Zotov AV, Saranin AA, Chou JP, Wei CM, Wang YL.  2011.  Interplay between adsorbed C-60 fullerenes and point defects on a Si(111)root 3 x root 3-In reconstructed surface, Dec. Surface Science. 605:2050-2054., Number 23-24 AbstractWebsite

Adsorption of C-60 onto Si(111)root 3 x root 3-In surface presents a fascinating example of interplay between molecular adsorbate and surface structural defects. It has been found that adsorbing C-60 molecules are trapped by the substitutional Si-defects. In turn, the group of a few adsorbed C-60 can act as a trap for the mobile vacancies of the root 3 x root 3-In reconstruction. Namely, adsorbed C-60 induces a strain in the indium layer, and when a mobile vacancy happens to get into the surface area surrounded by fullerenes, the In atoms between the C-60 and the vacancy shift from the T-4 to the H-3 sites, fixing a vacancy in a given location. (C) 2011 Elsevier B.V. All rights reserved.

Lin, PY, Shiau BW, Hsiao YF, Chen YC.  2011.  Creation of arbitrary spectra with an acousto-optic modulator and an injection-locked diode laser, Aug. Review of Scientific Instruments. 82:6., Number 8 AbstractWebsite

We use a double-passed acousto-optic modulator (AOM), driven by an arbitrary waveform generator to produce multiple frequency components for a laser with arbitrary frequency spacings. A programmed sequence containing various sections of radio-frequency sinusoidal signal at different frequency is applied to drive the AOM. The diffracted light is used to injection-lock a diode laser. The combined techniques allow us to generate the multi-line spectra for the diode laser with arbitrary frequency spacings in the range of 100 MHz at a relatively high output power of 80 mW and a small power variation of 2%. Such a light source can be used in the application for laser cooling of molecules. (C) 2011 American Institute of Physics. [doi:10.1063/1.3626903]

Xian, L, Barraza-Lopez S, Chou MY.  2011.  Effects of electrostatic fields and charge doping on the linear bands in twisted graphene bilayers, Aug. Physical Review B. 84:6., Number 7 AbstractWebsite

A twisted graphene bilayer consists of two graphene monolayers rotated by an angle. with respect to each other. Theory predicts that charge-neutral twisted graphene bilayers display a drastic reduction of their Fermi velocity v(F) for 0 less than or similar to 0 less than or similar to 20 degrees and 40 less than or similar to 0 less than or similar to 60 degrees. In this paper we present evidence for an additional anisotropic reduction of v(F) in the presence of external electrostatic fields. We also discuss in quantitative detail velocity renormalization for other relevant bands in the vicinity of the K point. Except for a rigid energy shift, electrostatic fields and doping by metal atoms give rise to similar renormalization of the band structure of twisted graphene bilayers.

Lai, MY, Chou JP, Utas OA, Denisov NV, Kotlyar VG, Gruznev D, Matetsky A, Zotov AV, Saranin AA, Wei CM, Wang YL.  2011.  Broken Even-Odd Symmetry in Self-Selection of Distances between Nanoclusters due to the Presence or Absence of Topological Solitons, Apr. Physical Review Letters. 106:4., Number 16 AbstractWebsite

Depositing particles randomly on a 1D lattice is expected to result in an equal number of particle pairs separated by even or odd lattice units. Unexpectedly, the even-odd symmetry is broken in the self-selection of distances between indium magic-number clusters on a Si(100)-2 x 1 reconstructed surface. Cluster pairs separated by even units are less abundant because they are linked by silicon atomic chains carrying topological solitons, which induce local strain and create localized electronic states with higher energy. Our findings reveal a unique particle-particle interaction mediated by the presence or absence of topological solitons on alternate lattices.

Lo, HY, Chen YC, Su PC, Chen HC, Chen JX, Yu IA, Chen YF.  2011.  Electromagnetically-induced-transparency-based cross-phase-modulation at attojoule levels, Apr. Physical Review A. 83:4., Number 4 AbstractWebsite

We report the experimental demonstration of electromagnetically-induced-transparency-based cross-phase-modulation at attojoule or, equivalently, few-hundred-photon levels. A phase shift of 0.005 rad of a probe pulse modulated by a signal pulse with an energy of similar to 100 aJ, equivalent to similar to 400 photons, was observed in a four-level system of cold (87)Rb atoms.

Chu, YY, Yu ZW, Zheng AM, Fang HJ, Zhang HL, Huang SJ, Liu SB, Deng F.  2011.  Acidic Strengths of Bronsted and Lewis Acid Sites in Solid Acids Scaled by P-31 NMR Chemical Shifts of Adsorbed Trimethylphosphine. Journal of Physical Chemistry C. 115:7660-7667.
Yang, CY, Chang CC, Feng ND, Huang SJ, Zheng AM, Chang YC, Lee KC, Deng F, Liu SB.  2011.  Acidity of Solid and Liquid Acids Probed by P-31 NMR Chemical Shifts of Phosphine Oxides. Journal of Analytical Science & Technology. 2:155-158.
Chouhan, N, Yeh CL, Hu SF, Huang JH, Liu RS, Chang WS, Chen KH.  2011.  Array of CdSe QD-sensitized ZnO nanorods serves as photoanode for water splitting. Chem. Commun.. 47:3493-3495.
Tu, WH, Hsu YK, Yen CH, Wu CI, Hwang JS, Chen LC, Chen KH.  2011.  Au nanoparticle modified GaN photoelectrode for photoelectrochemical hydrogen generation. Electrochem. Comm.. 13:530-533.
Feng, ND, Zheng AM, Wang QA, Ren PP, Gao XZ, Liu SB, Shen ZR, Chen TH, Deng F.  2011.  Boron Environments in B-Doped and (B, N)-Codoped TiO2 Photocatalysts: A Combined Solid-State NMR and Theoretical Calculation Study. Journal of Physical Chemistry C. 115:2709-2719.
Li, CC, Lin RJ, Lin HP, Chang CC, Lin YK, Chen LC, Chen KH.  2011.  Catalytic performance of plate-type Cu/Fe nanocomposites on ZnO nanorods for oxidative steam reforming of methanol. Chem. Comm.. 47:1473-1475.
Wu, JC, Chen CC, Chen KH, Chang* YC.  2011.  Controlled growth of aligned Alpha-helical polypeptide brushes for tunable electrical conductivity. ,Appl. Phys. Lett.. 98:133304.
Pimenov, SM, Frolov VD, Zavedeev EV, Abanshin NP, Du HY, Chen WC, Chen LC, Wu JJ, Chen KH.  2011.  Electron field emission properties of highly dense carbonnanotube arrays. Appl. Phys. A. 105:11.
Chattopadhyay, S, Chen LC, Chen KH.  2011.  Energy production and conversion applications ofone-dimensional semiconductor nanostructures. NPG Asia Mater.. 3:74-81.
Chong, CW, Hsu D, Chen WC, Li CC, Huang YF, Han HC, Lin JG, Chen LC, Chen KH, Chen YF.  2011.  Giant room temperature electric-field-assisted magnetoresistance in La0.7Sr0.3MnO3/n-Si nanotips heterojunctions. Nanotechnology. 22:125701.
Yu, NY, Ding Y, Lo AY, Huang SJ, Wu PH, C. L, Yin DH, Fu ZH, Yin DL, Hung CT, Lei ZB, Liu SB.  2011.  Gold nanoparticles supported on periodic mesoporous organosilicas for epoxidation of olefins: Effects of pore architecture and surface modification method of the supports. Microporous and Mesoporous Materials. 143:426-434.
Du, HY, Wang CH, Hsu HC, Chang ST, Yen SC, Chen LC, Viswanathan B, Chen* KH.  2011.  High performance of catalysts supported by directly grown PTFE-free micro-porous CNT layer in a proton exchange membrane fuel cell. J. Mater. Chem.. 21:2512-2516.
Cheng, H-C, Shiue R-J, Tsai C-C, Wang W-H, Chen Y-T.  2011.  High-quality graphene p-n junctions via resist-free fabrication and solution-based non-covalent functionalization. ACS Nano. 5:2051-2059.view pdf
Chen, YC, Hsu YK, Lin YG, Lin YK, Horng YY, Chen LC, Chen KH.  2011.  Highly flexible supercapacitors with manganese oxide nanosheet/carbon cloth electrode. Electrochem. Acta. 56:7124-7130.
Lo, HC, Hsiung HI, Chattopadhyay S, Han HC, Chen CF, Leu JP, Chen KH, Chen LC.  2011.  Label free sub-picomole level DNA detection with Ag nanoparticle decorated Au nanotip arrays as surface enhanced Raman spectroscopy platform. Biosensors and Bioelectronics. 26:2413-2418.
Li, L-C, Huang K-H, Wei J-A, Suen Y-W, Liu T-W, Chen C-C, Chen L-C, Chen K-H.  2011.  Low-frequency contact noise of GaN nanowire device detected by cross-spectrum technique. J. J. App. Phys.. 50:06GF21.
Lin, YG, Hsu YK, Lin YK, Chen SY, Chen LC, Chen* KH.  2011.  Microwave-activated CuO nanotip/ZnO nanorod nanoarchitectures embedded in a microreactor for efficient hydrogen production. J. Mater. Chem.. 21:324-326.
Chen, HM, Chen CK, Lin CC, Liu RS, Yang H, Chang WS, Chen KH, Chan TS, Lee JF, Tsai DP.  2011.  Multi-bandgap-sensitized ZnO nanorod photoelectrode arrays for water splitting: an X-ray absorption spectroscopy approach for the electronic evolution under solar illumination. J. Phys. Chem. C. 115:21971-21980.