Coauthored Publications with: Salamalai

Journal Article

Veerakumar, P, Salamalai K, Dhenadhayalan N, Lin K-C.  2019.  Catalytic Activity of Bimetallic (Ruthenium/Palladium) Nano-alloy Decorated Porous Carbons Toward Reduction of Toxic Compounds. Chemistry - An Asian Journal. 14(15):2662-2675. AbstractWebsite

Chicken feather-derived high-surface-area porous activated carbon (CFAC) material was prepared using chemical activation. A new composite composed of Ru-Pd nanoparticles supported on CFAC (Ru-Pd@CFAC) has been prepared by microwave-thermal reduction in the presence of the support. Characterization by XRD, Raman, BET, FE-SEM/TEM, FT-IR, TGA, XPS, HAADF-STEM-EDS, H2-chemisorption, H2-TPR, and ICP-AES was used to analyze the catalyst. This catalyst is found to be efficient for the reduction of hexavalent chromium (CrVI), potassium ferricyanide (K3[Fe(CN)6]), 4-nitrophenol (4-NP), and pendimethalin (PDM), at room temperature, and remains stable, even after several repeated runs. Moreover, it showed excellent catalytic activity compared with the monometallic counterparts. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Veerakumar, P, Salamalai K, Thanasekaran P, Lin K-C.  2018.  Simple Preparation of Porous Carbon-Supported Ruthenium: Propitious Catalytic Activity in the Reduction of Ferrocyanate(III) and a Cationic Dye. ACS Omega. 3:12609-12621., Number 10 AbstractWebsite

The present study involves the synthesis, characterization, and catalytic application of ruthenium nanoparticles (Ru NPs) supported on plastic-derived carbons (PDCs) synthesized from plastic wastes (soft drink bottles) as an alternative carbon source. PDCs have been further activated with CO2 and characterized by various analytical techniques. The catalytic activity of Ru@PDC for the reduction of potassium hexacyanoferrate(III), (K3[Fe(CN)6]), and new fuchsin (NF) dye by NaBH4 was performed under mild conditions. The PDCs had spherical morphology with an average size of 0.5 μm, and the Ru NP (5 ± 0.2 nm) loading (4.01 wt %) into the PDC provided high catalytic performance for catalytic reduction of ferrocyanate(III) and NF dye. This catalyst can be recycled more than six times with only a minor loss of its catalytic activity. In addition, the stability and reusability of the Ru@PDC catalyst are also discussed. Copyright © 2018 American Chemical Society.
Veerakumar, P, Jeyapragasam T, Surabhi S, Salamalai K, Maiyalagan T, Lin K-C.  2019.  Functionalized Mesoporous Carbon Nanostructures for Efficient Removal of Eriochrome Black-T from Aqueous Solution. Journal of Chemical and Engineering Data. 64(4):1305-1321. AbstractWebsite

Acid-functionalized mesoporous carbons (AF-MPCs) have been synthesized and used as adsorbents for removal of an azo dye, Eriochrome Black-T (EBT), from aqueous solution. To generate acid surface functionalities, mesoporous carbons (MPCs) were treated with sulfuric acid. Characterization of the samples was analyzed by XRD, Raman spectra, N 2 adsorption-desorption, FE-TEM, TGA, and FT-IR studies. The adsorption studies were carried out under various parameters, such as pH, adsorbent dosage, contact time, initial dye concentration solution temperature, and salt concentration. The results showed that the EBT adsorption onto samples was affected by the pH of solution; the maximum EBT ion adsorption took place at pH 1; and the adsorption uptake was increased with an increase in the initial dye concentration. Moreover, the mechanism of adsorption was investigated using kinetic, diffusion, and isotherm models. The best fit was obtained by the Langmuir model with high correlation coefficients (R 2 = 0.9463) with a maximum monolayer adsorption capacity of 117.0 mg·g -1 . The adsorbed anionic EBT dye molecules were eluted by ethanol solvent with the recovery percentage of 98%. Moreover, this study demonstrates that AF-MPCs can be successfully used as a low-cost adsorbent for the removal of EBT from aqueous solutions. © 2019 American Chemical Society.