Publications

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Hsu, YK, Chen YC, Lin YG, Chen LC, Chen KH.  2011.  Reversible phase transformation of MnO2nanosheets in electrochemical capacitor investigated by in-situ Raman spectroscopy. Chem. Comm.. 47:1252-1254.
Hsu, CH, Huang YF, Chen LC, Chattopadhyay* S, Chen KH, Lo HC, Chen CF.  2006.  Morphology control of Si nanotips fabricated by electron cyclotron resonance plasma etching. J. Vac. Sci. Technol. . B24:308-311.
Hsu, HC, Wang* CH, Nataraj SK, Huang HC, Du HY, Chang ST, Chen LC, Chen KH.  2012.  Stand-up structure of graphene-like carbon nanowalls on CNT directly grown on polyacrylonitrile-based carbon fiber paper as supercapacitor. Diamond Relat. Mater.. 25:176.
Hsu, YK, Yang JL, Lin YG, Chen SY, Chen LC, Chen* KH.  2009.  Electrophoretic deposition of PtRu nanoparticles on carbon nanotubes for methanol oxidation. Diamond Relat. Mater.. 18:557-562.
Hsu, Y-K, Chen Y-C, Lin Y-G, Chen L-C, Chen K-H.  2012.  High-cell-voltage supercapacitor of carbon nanotube/carbon cloth operating in neutral aqueous solution. Journal of Materials Chemistry. 22:3383-3387.
Hsu, CH, Lo HC, Chen CF, Wu CT, Hwang JH, Das D, Tsai J, Chen LC, Chen* KH.  2004.  Generally applicable self-masked dry etching technique for nanotip arrays formation. Nano Letters. 4:471-475.
Hu, ZG, Hess* P, Chen KH.  2007.  Optical properties of nanocrystalline diamond films from mid-infrared to ultraviolet using reflectometry and ellipsometry. J. Mater. Sci.: Mater. Electron. 48:37-41.
Hu, MS, Chen HL, Shen CH, Hong LS, Huang BR, Chen KH, Chen* LC.  2006.  Photosensitive gold nanoparticle-embedded dielectric nanowires. Nature Materials. 5:102-106.
Hu, MS, Kuo CC, Wu CT, Chen CW, Ang PK, Loh KP, Chen KH, Chen LC.  2011.  The production of SiC nanowalls sheathed with a few layers of strained graphene and their use in heterogeneous catalysis and sensing applications. Carbon. 49:4911-4919.
Hu, MS, Hsu GM, Chen* KH, Yu CJ, Hsu HC, Chen LC, Hwang JH, Hong LS, Chen YF.  2007.  Infrared lasing in InN nanobelts. Appl. Phys. Lett.. 90:123109.
Hu, MH, Wang WM, Chen TT, Hong LS, Chen CW, C.Chen C, Chen YF, Chen KH, Chen* LC.  2006.  Sharp infrared emission from single-crystalline indium nitride nanobelts derived by guided-stream thermal chemical vapor deposition. Adv. Func. Mater.. 16:537-541.
Huang, LW, Chang CK, Chien FC, Chen KH, Chen P, Chen FR, Chang CS.  2014.  Characterization of the cleaning process on a transferred graphene. J. Vac. Sci. Tech. A . 32:050601.
Huang, W-F, Chang S-T, Huang H-C, Wang C-H, Chen L-C, Chen K-H, Lin MC.  2020.  On the Reduction of O2 on Cathode Surfaces of Co–Corrin and Co–Porphyrin: A Computational and Experimental Study on Their Relative Efficiencies in H2O/H2O2 Formation, 2020. The Journal of Physical Chemistry CThe Journal of Physical Chemistry C. 124(8):4652-4659.: American Chemical Society AbstractWebsite
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Huang, H-C, Shown I, Chang S-T, Hsu H-C, Du H-Y, Kuo M-C, Wong K-T, Wang S-F, Wang C-H, Chen L-C, Chen K-H.  2012.  Pyrolyzed Cobalt Corrole as a Potential Non-Precious Catalyst for Fuel Cells. Adv. Funct. Mater.. 22:3500–3508.
Huang, YF, Chattopadhyay S, Jen YJ, Peng CY, Liu TA, Hsu YK, Pan CL, Lo HC, Hsu CH, Chang YH, Lee CS, Chen KH, Chen LC.  2007.  Improved broadband, and quasi-omnidirectional anti-reflection properties with biomimetic silicon nanostructures. Nature Nanotechnology. 2:770-774.
Huang, Y-F, Chattopadhyay* S, Hsu H-C, Wu C-T, Chen K-H, Chen L-C.  2011.  Origin and tuning of surface optic and long wavelength phonons in biomimetic GaAs nanotip arrays. Optical Materials Express. 1:535.
Huang, Y-F, Liao K-W, Fahmi FRZ, Modak VA, Tsai S-H, Ke S-W, Wang C-H, Chen L-C, Chen K-H.  2021.  Thickness-Dependent Photocatalysis of Ultra-Thin MoS2 Film for Visible-Light-Driven CO2 Reduction. Catalysts. 11, Number 11 AbstractWebsite

The thickness of transition metal dichalcogenides (TMDs) plays a key role in enhancing their photocatalytic CO2 reduction activity. However, the optimum thickness of the layered TMDs that is required to achieve sufficient light absorption and excellent crystallinity has still not been definitively determined. In this work, ultra-thin molybdenum disulfide films (MoS2TF) with 25 nm thickness presented remarkable photocatalytic activity, and the product yield increased by about 2.3 times. The photocatalytic mechanism corresponding to the TMDs’ thickness was also proposed. This work demonstrates that the thickness optimization of TMDs provides a cogent direction for the design of high-performance photocatalysts.

Huang, PJ, Chen CW, Chen JY, Chi GC, Pan* CJ, Kuo CC, Chen LC, Hsu CW, Chen KH, Hung SC, Chan CY, Pearton SJ, Ren F.  2009.  Optical and Structural Properties of Mg-ion Implanted GaN Nanowires. Vacuum. 83:797.
Huang, BR, Huang CS, Wu CC, Chen LC, Chen KH.  2004.  Electrical properties of annealed MPCVD grown vertically aligned carbon nanotubes films. Diamond & Related Materials. 13:2156-2159.
Huang, HM, Chen RS, Chen HY, Liu TW, Kuo CC, Chen CP, Hsu HC, Chen LC, Chen* KH, Yang YJ.  2010.  Photoconductivity in single AlN nanowires by sub-bandgap excitation. Appl. Phys. Lett.. 96:062104.
Huang, YF, Jen YJ, Chen LC, Chen KH, Chattopadhyay S.  2015.  Design for approaching cicada-wing reflectance in low and high index biomimetic nanostructures. ACS Nano . 9:301-311.
Huang, YF, Chen CY, Chen LC, Chen KH, Chattopadhyay S.  2014.  Plasmon management in index engineered 2.5D hybrid nanostructures for SERS. NPG Asia Materials. 6:e123.
Huang, BR, Chen KH, Ke WZ.  2000.  Surface-enhanced Raman analysis of the diamond films by using different metals. Materials Letters. 42:162-165.
Huang, H-C, Chang S-T, Hsu H-C, Du H-Y, Wang C-H, Chen L-C, Chen K-H.  2017.  Pyrolysis of Iron–Vitamin B9 As a Potential Nonprecious Metal Electrocatalyst for Oxygen Reduction Reaction. Search Results ACS Sustainable Chemistry & Engineering. 5 (4):2897–2905.
Huang, S-J, Muneeb A, Sabhapathy P, Bayikadi KS, Murtaza T, Raju K, Chen L-C, Chen K-H, Sankar R.  2021.  Two-Dimensional Layered NiLiP2S6 Crystals as an Efficient Bifunctional Electrocatalyst for Overall Water Splitting. Catalysts. 11, Number 7 AbstractWebsite

The quest of earth-abundant bifunctional electrocatalysts for highly efficient oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is essential for clean and renewable energy systems. Herein, directed by the experimental analysis, we demonstrate layered nickel lithium phosphosulfide (NiLiP2S6) crystal as a highly efficient water-splitting catalyst in alkaline media. With strained lattice due to stacked layers as observed by TEM and electronic structure analysis performed by XPS showed mixed Ni2+,3+ oxidation states induced by addition of Li as a cation, NiLiP2S6 displays excellent OER (current density of 10 mA cm–2 showed an overpotential of 303 mV vs. RHE and a Tafel slope of 114 mV dec–1) and HER activity (current density of −10 mA cm–2 showed an overpotential of 184 mV vs. RHE and a Tafel slope of 94.5 mV dec–1). Finally, an alkaline media was employed to demonstrate the overall water splitting using NiLiP2S6 as both the anode and the cathode, which attained a 50 mA cm−2 current density at 1.68 V. This bimetallic phosphosulfide, together with long-term stability and enhanced intrinsic activity, shows enormous potential in water splitting applications.