@article {4542, title = {Axial Chlorine Induced Electron Delocalization in Atomically Dispersed FeN4 Electrocatalyst for Oxygen Reduction Reaction with Improved Hydrogen Peroxide Tolerance}, journal = {Small}, year = {2023}, note = {

https://doi.org/10.1002/smll.202303598

}, month = {2023}, pages = {2303598}, publisher = {John Wiley \& Sons, Ltd}, abstract = {

Abstract Atomically dispersed iron sites on nitrogen-doped carbon (Fe-NC) are the most active Pt-group-metal-free catalysts for oxygen reduction reaction (ORR). However, due to oxidative corrosion and the Fenton reaction, Fe-NC catalysts are insufficiently active and stable. Herein, w e demonstrated that the axial Cl-modified Fe-NC (Cl-Fe-NC) electrocatalyst is active and stable for the ORR in acidic conditions with high H2O2 tolerance. The Cl-Fe-NC exhibits excellent ORR activity, with a high half-wave potential (E1/2) of 0.82~V versus a reversible hydrogen electrode (RHE), comparable to Pt/C (E1/2 = 0.85~V versus RHE) and better than Fe-NC (E1/2 = 0.79~V versus RHE). X-ray absorption spectroscopy analysis confirms that chlorine is axially integrated into the FeN4. More interestingly, compared to Fe-NC, the Fenton reaction is markedly suppressed in Cl-Fe-NC. In situ electrochemical impedance spectroscopy reveals that Cl-Fe-NC provides efficient electron transfer and faster reaction kinetics than Fe-NC. Density functional theory calculations reveal that incorporating Cl into FeN4 can drive the electron density delocalization of the FeN4 site, leading to a moderate adsorption free energy of OH* (?GOH*), d-band center, and a high onset potential, and promotes the direct four-electron-transfer ORR with weak H2O2 binding ability compared to Cl-free FeN4, indicating superior intrinsic ORR activity.

}, keywords = {Cl coordination, d-band center, electron density, FeN4, Fenton reaction, oxygen reduction reaction}, isbn = {1613-6810}, url = {https://doi.org/10.1002/smll.202303598}, author = {Sabhapathy, Palani and Raghunath, Puttikam and Sabbah, Amr and Indrajit Shown and Bayikadi, Khasim Saheb and Xie, Rui-Kun and Krishnamoorthy, Vimal and Lin, Ming-Chang and Kuei-Hsien Chen and Li-Chyong Chen} } @article {4069, title = {Enhanced thermoelectric performance of GeTe through in situ microdomain and Ge-vacancy control}, journal = {Journal of Materials Chemistry A}, volume = {7}, year = {2019}, note = {n/a}, month = {2019}, pages = {15181 - 15189}, publisher = {The Royal Society of Chemistry}, abstract = {

A highly reproducible sample preparation method for pure GeTe in a rhombohedral structure without converting to the cubic structure up to \~{}500 {\textdegree}C is reported to show control of the Ge-vacancy level and the corresponding herringbone-structured microdomains. The thermoelectric figure-of-merit (ZT) for GeTe powder could be raised from \~{}0.8 to 1.37 at high temperature (HT) near \~{}500 {\textdegree}C by tuning the Ge-vacancy level through the applied reversible in situ route, which made it highly controllable and reproducible. The enhanced ZT of GeTe was found to be strongly correlated with both its significantly increased Seebeck coefficient (\~{}161 μV K-1 at 500 {\textdegree}C) and reduced thermal conductivity (\~{}2.62 W m-1 K-1 at 500 {\textdegree}C) for a sample with nearly vacancy-free thicker herringbone-structured microdomains in the suppressed rhombohedral-to-cubic structure phase transformation. The microdomain and crystal structures were identified with HR-TEM (high-resolution transmission electron microscopy) and powder X-ray diffraction (XRD), while electron probe micro-analysis (EPMA) was used to confirm the stoichiometry changes of Ge : Te. Theoretical calculations for GeTe with various Ge-vacancy levels suggested that the Fermi level shifts toward the valence band as a function of increasing the Ge-vacancy level, which is consistent with the increased hole-type carrier concentration (n) and effective mass (m*) deduced from the Hall measurements. The uniquely prepared sample of a near-vacancy-free GeTe in a rhombohedral structure at high temperature favoured an enhanced Seebeck coefficient in view of the converging L- and Σ-bands of the heavy effective mass at the Fermi level, while the high density domain boundaries for the domain of low carrier density were shown to reduce the total thermal conductivity effectively.

}, isbn = {2050-7488}, url = {http://dx.doi.org/10.1039/C9TA03503F}, author = {Bayikadi, Khasim Saheb and Raman Sankar and Wu, Chien Ting and Xia, Chengliang and Chen, Yue and Li-Chyong Chen and Kuei-Hsien Chen and Fang-Cheng Chou} }