@article {doi:10.1021/acs.jpclett.0c01680, title = {Coherent-to-Incoherent Transition of Molecular Fluorescence Controlled by Surface Plasmon Polaritons}, journal = {J. Phys. Chem. Lett.}, volume = {11}, year = {2020}, note = {

PMID: 32619095

}, pages = {5948-5955}, abstract = {

n/a

}, doi = {10.1021/acs.jpclett.0c01680}, url = {https://doi.org/10.1021/acs.jpclett.0c01680}, author = {Wang,Siwei and Scholes,Gregory D.* and Hsu, Liang-Yan*} } @article {doi:10.1021/acs.jpclett.0c01989, title = {Controllable Frequency Dependence of Resonance Energy Transfer Coupled with Localized Surface Plasmon Polaritons}, journal = {J. Phys. Chem. Lett.}, volume = {11}, number = {16}, year = {2020}, note = {

PMID: 32787214

}, pages = {6796-6804}, abstract = {

n/a

}, doi = {10.1021/acs.jpclett.0c01989}, url = {https://doi.org/10.1021/acs.jpclett.0c01989}, author = {Lee, Ming-Wei and Hsu, Liang-Yan*} } @article {HSU2020, title = {Large-Scale Inhomogeneous Fluorescence Plasmonic Silver Chips: Origin and Mechanism}, journal = {Chem}, volume = {6}, year = {2020}, note = {

n/a

}, pages = {1-13}, abstract = {

Summary Large-scale inhomogeneous plasmonic metal chips have been demonstrated as a promising platform for biochemical sensing, but the origin of their strong fluorescence enhancements and average gap dependence is a challenging issue due to the complexity of modeling tremendous molecules within inhomogeneous gaps. To address this issue, we bridged microscopic mechanisms and macroscopic observations, developed a kinetic model, and experimentally investigated the fluorescence enhancement factors of IR800-streptavidin immobilized on metal nanoisland films (NIFs). Inspired by the kinetic model, we controlled the distribution of IR800-streptavidin within the valleys of NIFs by regioselective modification and achieved the fluorescence intensity enhancement up to 488-fold. The kinetic model allows us to qualitatively explain the mechanism of fluorescence intensity enhancements and quantitatively predict the trend of experimental enhancement factors, thereby determining the design principles of the plasmonic metal chips. Our study provides one key step further toward the sensing applications of large-scale plasmonic metal chips.

}, keywords = {biotin-streptavidin complex, chromophore, kinetic model, metal enhanced fluorescence, Nanostructure, Purcell effect, Quantum yield, regioselective modification, sensor, SPECTROSCOPY}, issn = {2451-9294}, doi = {https://doi.org/10.1016/j.chempr.2020.10.014}, url = {http://www.sciencedirect.com/science/article/pii/S2451929420305350}, author = {Hsu, Liang-Yan* and Yen, Hung-Chi and Lee, Ming-Wei and Sheu, Yae-lin and Po-Chun Chen and Dai, Hongjie * and Chen, Chia-Chun*} } @article {doi:10.1063/5.0007750, title = {Quantum transport with electronic relaxation in electrodes: Landauer-type formulas derived from the driven Liouville{\textendash}von Neumann approach}, journal = {J. Chem. Phys.}, volume = {153}, number = {4}, year = {2020}, note = {

n/a

}, pages = {044103}, abstract = {

n/a

}, doi = {10.1063/5.0007750}, url = {https://doi.org/10.1063/5.0007750}, author = {Chiang, Tse-Min and Hsu, Liang-Yan*} } @article {doi:10.1063/5.0027796, title = {Theory of molecular emission power spectra. I. Macroscopic quantum electrodynamics formalism}, journal = {J. Chem. Phys.}, volume = {153}, number = {18}, year = {2020}, note = {

n/a

}, pages = {184102}, abstract = {

n/a

}, doi = {10.1063/5.0027796}, url = {https://doi.org/10.1063/5.0027796}, author = {Wang,Siwei and Lee, Ming-Wei and Chuang,Yi-Ting and Scholes,Gregory D.* and Hsu, Liang-Yan*} } @article {doi:10.1021/acs.jpcc.9b08167, title = {Design of Plasmon Resonance Shifts by the Galvanic Replacement Degree of Au{\textendash}Ag Nanozappers}, journal = {J. Phys. Chem. C}, volume = {123}, number = {48}, year = {2019}, note = {

n/a

}, pages = {29298-29305}, abstract = {

n/a

}, doi = {10.1021/acs.jpcc.9b08167}, url = {https://doi.org/10.1021/acs.jpcc.9b08167}, author = {Yen, Hung-Chi and Su, Man-Nung and Liu, You-Cheng and Lee, Ming-Wei and Sheu, Yae-lin and Hsu, Liang-Yan* and Chen, Chia-Chun*} } @article {doi:10.1021/acs.jpcc.8b12555, title = {Electric Current Fluctuations Induced by Molecular Vibrations in the Adiabatic Limit: Molecular Dynamics-Driven Liouville von Neumann Approach}, journal = {J. Phys. Chem. C}, volume = {123}, number = {17}, year = {2019}, note = {

n/a

}, pages = {10746-10755}, abstract = {

We investigate time-dependent electron transport through a molecular junction in the adiabatic limit at the density-functional tight-binding level using the molecular dynamics-driven Liouville von Neumann (MD-DLvN) approach. When electron transport involves nuclear dynamics at finite temperature (\~{}70 K) within the NVE ensemble, we find that the steady-state current cannot be achieved even for a very short molecule (trans-fumaronitrile). Furthermore, to establish a relationship between electric current fluctuations and molecular vibrations, we analyze the similarities and differences between the current noise spectra and the MD power spectra. Our simulations show that not all normal modes can bring about current fluctuations. Furthermore, when a normal mode satisfies a particular symmetry, the normal mode can lead to frequency doubling of current fluctuations. This investigation offers new directions for studying electronic dynamics in a nonequilibrium open quantum system.

}, doi = {10.1021/acs.jpcc.8b12555}, url = {https://doi.org/10.1021/acs.jpcc.8b12555}, author = {Chiang, Tse-Min and Huang, Qian-Rui and Hsu, Liang-Yan*} } @article {doi:10.1063/1.5112095, title = {Photoinduced anomalous Coulomb blockade and the role of triplet states in electron transport through an irradiated molecular transistor. II. Effects of electron-phonon coupling and vibrational relaxation}, journal = {J. Chem. Phys.}, volume = {151}, number = {5}, year = {2019}, note = {

n/a

}, pages = {054704}, abstract = {

n/a

}, doi = {10.1063/1.5112095}, url = {https://doi.org/10.1063/1.5112095}, author = {Fu, Bo and Hsu, Liang-Yan*} } @article {doi:10.1063/1.5100014, title = {Quantum dynamics of a molecular emitter strongly coupled with surface plasmon polaritons: A macroscopic quantum electrodynamics approach}, journal = {J. Chem. Phys.}, volume = {151}, number = {1}, year = {2019}, note = {

n/a

}, pages = {014105}, abstract = {

n/a

}, doi = {10.1063/1.5100014}, url = {https://doi.org/10.1063/1.5100014}, author = {Wang,Siwei and Scholes,Gregory D.* and Hsu, Liang-Yan*} } @article {doi:10.1021/acs.jpclett.8b03429, title = {Characteristic Distance of Resonance Energy Transfer Coupled with Surface Plasmon Polaritons}, journal = {J. Phys. Chem. Lett.}, volume = {9}, number = {24}, year = {2018}, note = {

n/a

}, pages = {7032-7039}, abstract = {

n/a

}, doi = {10.1021/acs.jpclett.8b03429}, url = {https://doi.org/10.1021/acs.jpclett.8b03429}, author = {Wu, Jhih-Sheng and Yen-Cheng Lin and Sheu, Yae-lin and Hsu, Liang-Yan*} } @article {doi:10.1021/acs.nanolett.8b01838, title = {Photoinduced Anomalous Coulomb Blockade and the Role of Triplet States in Electron Transport through an Irradiated Molecular Transistor}, journal = {Nano Lett.}, volume = {18}, number = {8}, year = {2018}, note = {

PMID: 29995424

}, pages = {5015-5023}, abstract = {

n/a

}, doi = {10.1021/acs.nanolett.8b01838}, url = {https://doi.org/10.1021/acs.nanolett.8b01838}, author = {Fu, Bo and Mosquera, Mart{\'\i}n A. and Schatz, George C. and Ratner, Mark A. and Hsu, Liang-Yan*} } @article {doi:10.1021/acs.jpcc.8b07210, title = {Plasmon-Coupled Resonance Energy Transfer II: Exploring the Peaks and Dips in the Electromagnetic Coupling Factor}, journal = {J. Phys. Chem. C}, volume = {122}, number = {39}, year = {2018}, note = {

n/a

}, pages = {22650-22659}, abstract = {

n/a

}, doi = {10.1021/acs.jpcc.8b07210}, url = {https://doi.org/10.1021/acs.jpcc.8b07210}, author = {Ding, Wendu and Hsu, Liang-Yan* and Heaps, Charles W. and Schatz, George C.*} } @article {Ding2017, title = {Plasmon-coupled resonance energy transfer: A real-time electrodynamics approach}, journal = {J. Chem. Phys.}, volume = {146}, number = {6}, year = {2017}, month = {FEB 14}, pages = {064109}, issn = {0021-9606}, doi = {10.1063/1.4975815}, author = {Ding, Wendu and Hsu, Liang-Yan* and Schatz, George C.*} } @article {Sheu2017, title = {Entropy-based time-varying window width selection for nonlinear-type time-frequency analysis}, journal = {Int. J. Data Sci. Anal. (JDSA)}, volume = {3}, number = {4}, year = {2017}, note = {

n/a

}, pages = {231{\textendash}245}, abstract = {

We propose a time-varying optimal window width (TVOWW) and an adaptive optimal window width selection schemes to optimize the performance of several nonlinear-type time-frequency analyses, including the reassignment method and its variations. A window rendering the most concentrated distribution in the time-frequency representation is regarded as the optimal window. The TVOWW selection scheme is particularly useful for signals that comprise fast-varying instantaneous frequencies and small spectral gaps. To demonstrate the efficacy of the method, in addition to analyzing synthetic signals, we study an atomic time-varying dipole moment driven by two-color mid-infrared laser fields in attosecond physics and near-threshold harmonics of a hydrogen atom in the strong laser field.

}, issn = {2364-4168}, url = {http://dx.doi.org/10.1007/s41060-017-0053-2}, author = {Sheu, Yae-lin and Hsu, Liang-Yan and Chou, Pi-Tai and Wu, Hau-tieng*} } @article {2741, title = {Plasmon-Coupled Resonance Energy Transfer}, journal = {J. Phys. Chem. Lett.}, volume = {8}, number = {10}, year = {2017}, pages = {2357{\textendash}2367}, publisher = {American Chemical Society}, issn = {1948-7185}, doi = {10.1021/acs.jpclett.7b00526}, url = {http://dx.doi.org/10.1021/acs.jpclett.7b00526}, author = {Hsu, Liang-Yan and Ding, Wendu and Schatz, George C.*} } @article {2803, title = {Reaction: New Insights into Molecular Electronics}, journal = {Chem}, volume = {3}, year = {2017}, pages = {378-379}, author = {Hsu, L.-Y. and Jin, B.-Y. and C.-H. Chen and Peng, S.-M.*} } @article {Hsu2016, title = {Theory of molecular conductance using a modular approach}, journal = {J. Chem. Phys.}, volume = {145}, number = {23}, year = {2016}, note = {

n/a

}, month = {DEC 21}, pages = {234702 }, abstract = {

n/a

}, issn = {0021-9606}, doi = {10.1063/1.4972131}, author = {Hsu, Liang-Yan* and Rabitz, Herschel*} } @article {Hsu2016a, title = {Conductance and activation energy for electron transport in series and parallel intramolecular circuits}, journal = {Phys. Chem. Chem. Phys.}, volume = {18}, number = {47}, year = {2016}, note = {

n/a

}, pages = {32087-32095}, abstract = {

n/a

}, issn = {1463-9076}, doi = {10.1039/c6cp06362d}, author = {Hsu, Liang-Yan* and Wu, Ning and Rabitz, Herschel*} } @article {Sheu2015, title = {Exploring laser-driven quantum phenomena from a time-frequency analysis perspective: a comprehensive study}, journal = {Opt. Express}, volume = {23}, number = {23}, year = {2015}, note = {n/a}, month = {NOV 16}, pages = {30459-30482}, abstract = {n/a}, issn = {1094-4087}, doi = {10.1364/OE.23.030459}, author = {Sheu, Yae-lin and Wu, Hau-tieng and Hsu, Liang-Yan} } @article {Liao2015, title = {Molecular Series-Tunneling Junctions}, journal = {J. Am. Chem. Soc.}, volume = {137}, number = {18}, year = {2015}, note = {n/a}, month = {MAY 13}, pages = {5948-5954}, abstract = {n/a}, issn = {0002-7863}, doi = {10.1021/jacs.5b00448}, author = {Liao, Kung-Ching and Hsu, Liang-Yan and Bowers, Carleen M. and Rabitz, Herschel and Whitesides, George M.} } @article {Hsu2015a, title = {Gate Control of Artificial Single-Molecule Electric Machines}, journal = {J. Phys. Chem. C}, volume = {119}, number = {9}, year = {2015}, note = {n/a}, month = {MAR 5}, pages = {4573-4579}, abstract = {n/a}, issn = {1932-7447}, doi = {10.1021/jp511941w}, author = {Hsu, Liang-Yan and Chen, Chun-Yin and Li, Elise Y. and Rabitz, Herschel} } @article {Hsu2015, title = {Coherent revival of tunneling}, journal = {Phys. Rev. B}, volume = {92}, number = {3}, year = {2015}, note = {n/a}, month = {JUL 8}, abstract = {n/a}, issn = {2469-9950}, doi = {10.1103/PhysRevB.92.035410}, author = {Hsu, Liang-Yan and Rabitz, Herschel} } @article {Ting2015, title = {Energy-Level Alignment for Single-Molecule Conductance of Extended Metal-Atom Chains}, journal = {Angew. Chem. Int. Ed.}, volume = {54}, number = {52}, year = {2015}, note = {n/a}, month = {DEC 21}, pages = {15734-15738}, abstract = {n/a}, issn = {1433-7851}, doi = {10.1002/anie.201508199}, author = {Ting, Ta-Cheng and Hsu, Liang-Yan and Huang, Min-Jie and Horng, Er-Chien and Lu, Hao-Cheng and Hsu, Chan-Hsiang and Jiang, Ching-Hong and Jin, Bih-Yaw and Peng, Shie-Ming and Chen, Chun-hsien} } @article {Hsu2015b, title = {Coherent light-driven electron transport through polycyclic aromatic hydrocarbon: laser frequency, field intensity, and polarization angle dependence}, journal = {Phys. Chem. Chem. Phys.}, volume = {17}, number = {32}, year = {2015}, note = {n/a}, pages = {20617-20629}, abstract = {n/a}, issn = {1463-9076}, doi = {10.1039/c5cp02663f}, author = {Hsu, Liang-Yan and Rabitz, Herschel} } @article {Hsu2014, title = {Light-driven electron transport through a molecular junction based on cross-conjugated systems}, journal = {J. Chem. Phys.}, volume = {141}, number = {12}, year = {2014}, note = {n/a}, month = {SEP 28}, abstract = {n/a}, issn = {0021-9606}, doi = {10.1063/1.4895963}, author = {Hsu, Liang-Yan and Xie, Dan and Rabitz, Herschel} } @article {Sheu2014, title = {A new time-frequency method to reveal quantum dynamics of atomic hydrogen in intense laser pulses: Synchrosqueezing transform}, journal = {AIP Advances}, volume = {4}, number = {11}, year = {2014}, note = {n/a}, month = {NOV}, abstract = {n/a}, issn = {2158-3226}, doi = {10.1063/1.4903164}, author = {Sheu, Yae-lin and Hsu, Liang-Yan and Wu, Hau-tieng and Li, Peng-Cheng and Chu, Shih-I} } @article {Hsu2014a, title = {Gate Control of the Conduction Mechanism Transition from Tunneling to Thermally Activated Hopping}, journal = {J. Phys. Chem. Lett.}, volume = {5}, number = {11}, year = {2014}, note = {n/a}, month = {JUN 5}, pages = {1831-1836}, abstract = {n/a}, issn = {1948-7185}, doi = {10.1021/jz5005818}, author = {Hsu, Liang-Yan and Wu, Ning and Rabitz, Herschel} } @article {Huang2014, title = {Conductance of Tailored Molecular Segments: A Rudimentary Assessment by Landauer Formulation}, journal = {J. Am. Chem. Soc.}, volume = {136}, number = {5}, year = {2014}, note = {n/a}, month = {FEB 5}, pages = {1832-1841}, abstract = {n/a}, issn = {0002-7863}, doi = {10.1021/ja4088538}, author = {Huang, Min-Jie and Hsu, Liang-Yan and Fu, Ming-Dung and Chuang, Su-Ting and Tien, Fang-Wei and Chen, Chun-hsien} } @article {Hsu2013, title = {Single-Molecule Electric Revolving Door}, journal = {Nano Lett.}, volume = {13}, number = {11}, year = {2013}, note = {n/a}, month = {NOV}, pages = {5020-5025}, abstract = {n/a}, issn = {1530-6984}, doi = {10.1021/nl401340c}, author = {Hsu, Liang-Yan and Li, Elise Y. and Rabitz, Herschel} } @article {Hsu2012, title = {Single-Molecule Phenyl-Acetylene-Macrocycle-Based Optoelectronic Switch Functioning as a Quantum-Interference-Effect Transistor}, journal = {Phys. Rev. Lett.}, volume = {109}, number = {18}, year = {2012}, note = {n/a}, month = {OCT 31}, abstract = {n/a}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.109.186801}, author = {Hsu, Liang-Yan and Rabitz, Herschel} } @article {Hsu2010, title = {Transport through a mixed-valence molecular transistor in the sequential-tunneling regime: Theoretical insight from the two-site Peierls-Hubbard model}, journal = {J. Chem. Phys.}, volume = {133}, number = {14}, year = {2010}, note = {

n/a

}, month = {OCT 14}, abstract = {

n/a

}, issn = {0021-9606}, doi = {10.1063/1.3499746}, author = {Hsu, Liang-Yan* and Tsai, Te-Wei and Jin, Bih-Yaw*} } @article {Hsu2009, title = {An investigation of quantum transport by the free-electron network model: Resonance and interference effects}, journal = {Chem. Phys.}, volume = {355}, number = {2-3}, year = {2009}, note = {

n/a

}, month = {JAN 27}, pages = {177-182}, abstract = {

n/a

}, issn = {0301-0104}, doi = {10.1016/j.chemphys.2008.12.015}, author = {Hsu, Liang-Yan and Jin, Bih-Yaw*} } @article {Hsu2008a, title = {Bandwidth, intensity, and lineshape of the transmission spectrum in the single molecular junction}, journal = {Chem. Phys. Lett.}, volume = {457}, number = {1-3}, year = {2008}, note = {

n/a

}, month = {MAY 20}, pages = {279-283}, abstract = {

n/a

}, issn = {0009-2614}, doi = {10.1016/j.cplett.2008.04.025}, author = {Hsu, Liang-Yan and Jin, Bih-Yaw*} } @article {Hsu2008, title = {Charge transport through a single molecular wire based on linear multimetal complexes: A Non-Equilibrium Green{\textquoteright}s Function approach}, journal = {J. Phys. Chem. C}, volume = {112}, number = {28}, year = {2008}, note = {

n/a

}, month = {JUL 17}, pages = {10538-10541}, abstract = {

n/a

}, issn = {1932-7447}, doi = {10.1021/jp801926d}, author = {Hsu, Liang-Yan and Huang, Qian-Rui and Jin, Bih-Yaw*} }