<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="6.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Yvon, K.</style></author><author><style face="normal" font="default" size="100%">Rapin, J. P.</style></author><author><style face="normal" font="default" size="100%">Penin, N.</style></author><author><style face="normal" font="default" size="100%">Ma, Z.</style></author><author><style face="normal" font="default" size="100%">Chou, M. Y.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">LaMg2PdH7, a new complex metal hydride containing tetrahedral PdH4 (4-) anions</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Alloys and Compounds</style></secondary-title><alt-title><style face="normal" font="default" size="100%">J. Alloy. Compd.</style></alt-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">crystal structure</style></keyword><keyword><style  face="normal" font="default" size="100%">FILMS</style></keyword><keyword><style  face="normal" font="default" size="100%">metal hydrides</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2007</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Oct</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">&lt;Go to ISI&gt;://WOS:000250822900009</style></url></web-urls></urls><volume><style face="normal" font="default" size="100%">446</style></volume><pages><style face="normal" font="default" size="100%">34-38</style></pages><isbn><style face="normal" font="default" size="100%">0925-8388</style></isbn><language><style face="normal" font="default" size="100%">English</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Hydrogenation of the inten-netallic compound LaMg2Pd at 200 degrees C and 10 bar leads to a complex metal hydride of composition LaMg2PdH7. Its structure has orthorhombic symmetry and displays tetrahedral [PdH4](4-) anions. The Pd-H bond distances as measured on the deuteride range from 1.71 to 1.78 angstrom and the H-Pd-H bond angles from 95 degrees to 122 degrees. Three additional hydride anions H- occupy La2Mg2-type interstices having tetrahedral metal configurations. Band structure calculations suggest the hydride to be non-metallic and to have a band gap of similar to 1.0ev. The compound desorbs hydrogen at 125 degrees C yielding a pressure of more than I bar absolute. (C) 2006 Elsevier B.V. All rights reserved.&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article; Proceedings Paper</style></work-type><accession-num><style face="normal" font="default" size="100%">WOS:000250822900009</style></accession-num><notes><style face="normal" font="default" size="100%">&lt;p&gt;ISI Document Delivery No.: 229RWTimes Cited: 5Cited Reference Count: 14Cited References:      Yvon K, 2005, PHYS REV LETT, V94, DOI 10.1103/PhysRevLett.94.066403     RODRIGUEZCARVAJ.J, 2005, FULLPROF SUITE LLB S     YVON K, 2005, HYDRIDES SOLID STATE, P1814     Favre-Nicolin V, 2002, J APPL CRYSTALLOGR, V35, P734, DOI 10.1107/S0021889802015236     Cerny R, 2002, J ALLOY COMPD, V340, P180, DOI 10.1016/S0925-8388(02)00050-6     Isidorsson J, 2002, APPL PHYS LETT, V80, P2305, DOI 10.1063/1.1463205     Richardson TJ, 2002, APPL PHYS LETT, V80, P1349, DOI 10.1063/1.1454218     Olofsson-Martensson M, 1999, J AM CHEM SOC, V121, P10908, DOI 10.1021/ja991047r     Kresse G, 1996, COMP MATER SCI, V6, P15, DOI 10.1016/0927-0256(96)00008-0     BRONGER W, 1995, J ALLOY COMPD, V228, P119, DOI 10.1016/0925-8388(95)01670-8     KRESSE G, 1994, PHYS REV B, V49, P14251, DOI 10.1103/PhysRevB.49.14251     NOREUS D, 1988, J LESS-COMMON MET, V139, P233, DOI 10.1016/0022-5088(88)90004-5     OLOFSON M, 1988, INORG CHEM, V37, P2900     ZOLLIKER P, 1986, INORG CHEM, V25, P3590, DOI 10.1021/ic00240a012Yvon, K. Rapin, J. -Ph. Penin, N. Ma, Zhu Chou, M. Y.10th International Symposium on Metal-Hydrogen Systems, Fundamentals and ApplicationsOCT 01-06, 2006Lahaina, HIGM Res &amp;amp; Dev, Hawaii Hydrogen Carriers, LLC, Hy Energy, LLC, Jet Propuls Lab, NIST Ctr Neutron Res, Suzuki Shokan Co, Ltd, Toyota Motor SalesELSEVIER SCIENCE SALAUSANNESI&lt;/p&gt;
</style></notes><auth-address><style face="normal" font="default" size="100%">Univ Geneva, Lab Cristallog, CH-1211 Geneva 4, Switzerland. Georgia Inst Technol, Sch Phys, Atlanta, GA 30332 USA.Yvon, K (reprint author), Univ Geneva, Lab Cristallog, 24 Quai E Ansermet, CH-1211 Geneva 4, Switzerlandklaus.yvon@cryst.unige.ch</style></auth-address></record></records></xml>