@article {1425,
	title = {LaMg2PdH7, a new complex metal hydride containing tetrahedral PdH4 (4-) anions},
	journal = {Journal of Alloys and Compounds},
	volume = {446},
	year = {2007},
	note = {<p>ISI Document Delivery No.: 229RWTimes Cited: 5Cited Reference Count: 14Cited References:      Yvon K, 2005, PHYS REV LETT, V94, DOI 10.1103/PhysRevLett.94.066403     RODRIGUEZCARVAJ.J, 2005, FULLPROF SUITE LLB S     YVON K, 2005, HYDRIDES SOLID STATE, P1814     Favre-Nicolin V, 2002, J APPL CRYSTALLOGR, V35, P734, DOI 10.1107/S0021889802015236     Cerny R, 2002, J ALLOY COMPD, V340, P180, DOI 10.1016/S0925-8388(02)00050-6     Isidorsson J, 2002, APPL PHYS LETT, V80, P2305, DOI 10.1063/1.1463205     Richardson TJ, 2002, APPL PHYS LETT, V80, P1349, DOI 10.1063/1.1454218     Olofsson-Martensson M, 1999, J AM CHEM SOC, V121, P10908, DOI 10.1021/ja991047r     Kresse G, 1996, COMP MATER SCI, V6, P15, DOI 10.1016/0927-0256(96)00008-0     BRONGER W, 1995, J ALLOY COMPD, V228, P119, DOI 10.1016/0925-8388(95)01670-8     KRESSE G, 1994, PHYS REV B, V49, P14251, DOI 10.1103/PhysRevB.49.14251     NOREUS D, 1988, J LESS-COMMON MET, V139, P233, DOI 10.1016/0022-5088(88)90004-5     OLOFSON M, 1988, INORG CHEM, V37, P2900     ZOLLIKER P, 1986, INORG CHEM, V25, P3590, DOI 10.1021/ic00240a012Yvon, K. Rapin, J. -Ph. Penin, N. Ma, Zhu Chou, M. Y.10th International Symposium on Metal-Hydrogen Systems, Fundamentals and ApplicationsOCT 01-06, 2006Lahaina, HIGM Res \&amp; Dev, Hawaii Hydrogen Carriers, LLC, Hy Energy, LLC, Jet Propuls Lab, NIST Ctr Neutron Res, Suzuki Shokan Co, Ltd, Toyota Motor SalesELSEVIER SCIENCE SALAUSANNESI</p>
},
	month = {Oct},
	pages = {34-38},
	type = {Article; Proceedings Paper},
	abstract = {<p>Hydrogenation of the inten-netallic compound LaMg2Pd at 200 degrees C and 10 bar leads to a complex metal hydride of composition LaMg2PdH7. Its structure has orthorhombic symmetry and displays tetrahedral [PdH4](4-) anions. The Pd-H bond distances as measured on the deuteride range from 1.71 to 1.78 angstrom and the H-Pd-H bond angles from 95 degrees to 122 degrees. Three additional hydride anions H- occupy La2Mg2-type interstices having tetrahedral metal configurations. Band structure calculations suggest the hydride to be non-metallic and to have a band gap of similar to 1.0ev. The compound desorbs hydrogen at 125 degrees C yielding a pressure of more than I bar absolute. (C) 2006 Elsevier B.V. All rights reserved.</p>
},
	keywords = {crystal structure, FILMS, metal hydrides},
	isbn = {0925-8388},
	url = {<Go to ISI>://WOS:000250822900009},
	author = {Yvon, K. and Rapin, J. P. and Penin, N. and Ma, Z. and Chou, M. Y.}
}
