<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="6.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Muthiah, B.</style></author><author><style face="normal" font="default" size="100%">Paredes-Roibás, D.</style></author><author><style face="normal" font="default" size="100%">Kasai, T.</style></author><author><style face="normal" font="default" size="100%">King-Chuen Lin</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Photodissociation of CH2BrI using cavity ring-down spectroscopy: in search of a BrI elimination channel</style></title><secondary-title><style face="normal" font="default" size="100%">Physical Chemistry Chemical Physics</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2019</style></year></dates><urls><web-urls><url><style face="normal" font="default" size="100%">https://www.scopus.com/record/display.uri?eid=2-s2.0-85068503890&amp;doi=10.1039%2fc8cp04130j&amp;origin=inward&amp;txGid=7fc601f269b93a6934e081b9c9354299</style></url></web-urls></urls><volume><style face="normal" font="default" size="100%">21</style></volume><pages><style face="normal" font="default" size="100%">13943-13949</style></pages><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Photodissociation of CH2BrI was investigated in search of unimolecular elimination of BrI via a primary channel using cavity ring-down absorption spectroscopy (CRDS) at 248 nm. The BrI spectra were acquired involving the first three ground vibrational levels corresponding to A3Π1 ← X1Σ+ transition. With the aid of spectral simulation, the BrI rotational lines were assigned. The nascent vibrational populations for v′′ = 0, 1, and 2 levels are obtained with a population ratio of 1:(0.58 ± 0.10):(0.34 ± 0.05), corresponding to a Boltzmann-like vibrational temperature of 713 ± 49 K. The quantum yield of the ground state BrI elimination reaction is determined to be 0.044 ± 0.014. The CCSD(T)//B3LYP/MIDI! method was employed to explore the potential energy surface for the unimolecular elimination of BrI from CH2BrI.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">26</style></issue></record></records></xml>