<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="6.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Liu, Y.-T.</style></author><author><style face="normal" font="default" size="100%">Tsai, M.-T.</style></author><author><style face="normal" font="default" size="100%">Liu, C.-Y.</style></author><author><style face="normal" font="default" size="100%">Tsai, P.-Y.</style></author><author><style face="normal" font="default" size="100%">Lin, K.-C.</style></author><author><style face="normal" font="default" size="100%">Shih, Y.H.</style></author><author><style face="normal" font="default" size="100%">A.H.H. Chang</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Photodissociation of gaseous acetyl chloride at 248 nm by time-resolved fourier-transform infrared spectroscopy: The HCl, CO, and CH2 product channels</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Physical Chemistry A</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Acetates</style></keyword><keyword><style  face="normal" font="default" size="100%">acetic acid derivative</style></keyword><keyword><style  face="normal" font="default" size="100%">Acetic Acids</style></keyword><keyword><style  face="normal" font="default" size="100%">Acetyl chloride</style></keyword><keyword><style  face="normal" font="default" size="100%">argon</style></keyword><keyword><style  face="normal" font="default" size="100%">Article</style></keyword><keyword><style  face="normal" font="default" size="100%">carbon monoxide</style></keyword><keyword><style  face="normal" font="default" size="100%">Chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">chloride</style></keyword><keyword><style  face="normal" font="default" size="100%">Chlorides</style></keyword><keyword><style  face="normal" font="default" size="100%">Chlorine compounds</style></keyword><keyword><style  face="normal" font="default" size="100%">CL reaction</style></keyword><keyword><style  face="normal" font="default" size="100%">Dissociation channels</style></keyword><keyword><style  face="normal" font="default" size="100%">Emission spectroscopy</style></keyword><keyword><style  face="normal" font="default" size="100%">Fourier Transform Infrared</style></keyword><keyword><style  face="normal" font="default" size="100%">Fourier transforms</style></keyword><keyword><style  face="normal" font="default" size="100%">GAS</style></keyword><keyword><style  face="normal" font="default" size="100%">Gases</style></keyword><keyword><style  face="normal" font="default" size="100%">Ground electronic state</style></keyword><keyword><style  face="normal" font="default" size="100%">High-resolution spectra</style></keyword><keyword><style  face="normal" font="default" size="100%">hydrochloric acid</style></keyword><keyword><style  face="normal" font="default" size="100%">Infrared emission spectroscopy</style></keyword><keyword><style  face="normal" font="default" size="100%">infrared spectroscopy</style></keyword><keyword><style  face="normal" font="default" size="100%">Internal conversions</style></keyword><keyword><style  face="normal" font="default" size="100%">Internal energies</style></keyword><keyword><style  face="normal" font="default" size="100%">Orders of magnitude</style></keyword><keyword><style  face="normal" font="default" size="100%">OXYGEN</style></keyword><keyword><style  face="normal" font="default" size="100%">PHOTOCHEMISTRY</style></keyword><keyword><style  face="normal" font="default" size="100%">Photodissociation</style></keyword><keyword><style  face="normal" font="default" size="100%">Pressure dependence</style></keyword><keyword><style  face="normal" font="default" size="100%">Product channel</style></keyword><keyword><style  face="normal" font="default" size="100%">rotation</style></keyword><keyword><style  face="normal" font="default" size="100%">Secondary dissociation</style></keyword><keyword><style  face="normal" font="default" size="100%">SPECTROSCOPY</style></keyword><keyword><style  face="normal" font="default" size="100%">TIME</style></keyword><keyword><style  face="normal" font="default" size="100%">Time Factors</style></keyword><keyword><style  face="normal" font="default" size="100%">Time-resolved</style></keyword><keyword><style  face="normal" font="default" size="100%">vibration</style></keyword><keyword><style  face="normal" font="default" size="100%">Wavelet transforms</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2010</style></year></dates><urls><web-urls><url><style face="normal" font="default" size="100%">https://www.scopus.com/inward/record.uri?eid=2-s2.0-77954448374&amp;doi=10.1021%2fjp1030653&amp;partnerID=40&amp;md5=bae7fd207ac95f19ef630f1ad94dd04b</style></url></web-urls></urls><number><style face="normal" font="default" size="100%">27</style></number><volume><style face="normal" font="default" size="100%">114</style></volume><pages><style face="normal" font="default" size="100%">7275-7283</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;In one-photon dissociation of gaseous acetyl chloride at 248 nm, time-resolved Fourier-transform infrared emission spectroscopy is used to detect the fragments of HCl, CO, and CH2 in the presence of Ar or O 2. The high-resolution spectra of HCl and CO are analyzed to yield the corresponding internal energy deposition of 8.9 ± 1.1 and 6.2 ± 0.9 kcal/mol. The presence of the CH2 fragment is verified by detecting the CO2 product resulting from the reaction of CH 2 and the added O2. The probability of the HCl formation via a hot Cl reaction with the precursor is examined to be negligible by performing two experiments, the CH3COCl pressure dependence and the measurement of Br2 with Cl reaction. The HCl elimination channel under the Ar addition is verified to be slowed by 2 orders of magnitude, as compared to the Cl elimination channel. The observed fragments are proposed to dissociate on the hot ground electronic state via collision-induced internal conversion. A two-body dissociation channel is favored leading to HCl and CH2CO, followed by secondary dissociation. © 2010 American Chemical Society.&lt;/p&gt;
</style></abstract><notes><style face="normal" font="default" size="100%">&lt;p&gt;cited By 12&lt;/p&gt;
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