<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="6.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Tsai, P.-Y.</style></author><author><style face="normal" font="default" size="100%">Lin, K.-C.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Note: Photodissociation of CH3COCN at 308 nm by time-resolved Fourier-transform infrared emission spectroscopy: Is CO a primary or secondary product?</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Chemical Physics</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Branching ratio</style></keyword><keyword><style  face="normal" font="default" size="100%">carbon monoxide</style></keyword><keyword><style  face="normal" font="default" size="100%">Chemical reactions</style></keyword><keyword><style  face="normal" font="default" size="100%">Chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">cyanide</style></keyword><keyword><style  face="normal" font="default" size="100%">Cyanides</style></keyword><keyword><style  face="normal" font="default" size="100%">Emission spectroscopy</style></keyword><keyword><style  face="normal" font="default" size="100%">Fourier transform infra reds</style></keyword><keyword><style  face="normal" font="default" size="100%">Fourier Transform Infrared</style></keyword><keyword><style  face="normal" font="default" size="100%">infrared spectroscopy</style></keyword><keyword><style  face="normal" font="default" size="100%">letter</style></keyword><keyword><style  face="normal" font="default" size="100%">Photochemical Processes</style></keyword><keyword><style  face="normal" font="default" size="100%">PHOTOCHEMISTRY</style></keyword><keyword><style  face="normal" font="default" size="100%">Photodissociation</style></keyword><keyword><style  face="normal" font="default" size="100%">Prior distribution</style></keyword><keyword><style  face="normal" font="default" size="100%">Reactant molecules</style></keyword><keyword><style  face="normal" font="default" size="100%">Secondary product</style></keyword><keyword><style  face="normal" font="default" size="100%">SPECTROSCOPY</style></keyword><keyword><style  face="normal" font="default" size="100%">Theoretical aspects</style></keyword><keyword><style  face="normal" font="default" size="100%">TIME</style></keyword><keyword><style  face="normal" font="default" size="100%">Time Factors</style></keyword><keyword><style  face="normal" font="default" size="100%">Transition state</style></keyword><keyword><style  face="normal" font="default" size="100%">Vibrational energy distribution</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2013</style></year></dates><urls><web-urls><url><style face="normal" font="default" size="100%">https://www.scopus.com/inward/record.uri?eid=2-s2.0-84879913792&amp;doi=10.1063%2f1.4812378&amp;partnerID=40&amp;md5=bbc6634ce42a1501a43d1e43de04a145</style></url></web-urls></urls><number><style face="normal" font="default" size="100%">24</style></number><volume><style face="normal" font="default" size="100%">138</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;This Note aims to clarify the source of CO in photodissociation of acetyl cyanide (CH3COCN) at 308 nm. From the theoretical aspects, a new pathway via isomerization transition state (TS) at 391 ± 8 kJ/mol is found leading to the CO + CH3NC products. An amount of 60% reactant molecules at 300 K is estimated to successfully surpass the average TS barrier lying above the excitation energy by 3.5 kJ/mol. Further, a prior distribution method is conducted to characterize the vibrational energy distribution of CO on a statistical basis. The pathway to CH3NC + CO yields a vibrational branching ratio (v = 0:v = 1:v = 2:v = 3∼0.63:0.25:0.093:0.032) in excellent agreement with the observation (0.62:0.25:0.09:0.05). © 2013 AIP Publishing LLC.&lt;/p&gt;
</style></abstract><notes><style face="normal" font="default" size="100%">&lt;p&gt;cited By 1&lt;/p&gt;
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