@article {Tsai20118857,
	title = {Doublet rotational energy transfer of the SH (X 2Π, v'' = 0) state by collisions with Ar},
	journal = {Physical Chemistry Chemical Physics},
	volume = {13},
	number = {19},
	year = {2011},
	note = {<p>cited By 1</p>
},
	pages = {8857-8868},
	abstract = {<p>The rotational energy transfer (RET) by Ar collisions within the SH X 2Π (v'' = 0, J'' = 0.5-10.5) state is characterized. The integral cross sections as a function of collision energy for each rotational transition are calculated using a quantum scattering method in which the constructed potential energy functions are based on a ground state potential energy surface (PES) reported previously. On the other hand, a laser-induced excitation fluorescence technique is employed to monitor the relaxation of the rotational population as a function of photolysis-probe delay time following the photodissociation of H2S at 248 nm. The rotational population evolution is comparable to its theoretical counterpart based on calculated Λ-resolved RET rate constants. The propensity in Λ-resolved RET transitions is found to approximately resemble the case of OH(X 2Π, v'' = 0) + Ar. The Λ-averaged RET collisions are also analyzed and result in several propensity rules in the transitions. Most propensity rules are similar to those observed in the collisions of SH(A 2Σ+) by Ar. However, the behavior of the conserving ratio, defined as rate constants for spin-orbit conserving transition divided by those for spin-orbit changing transition, shows distinct difference from those described by Hund{\textquoteright}s case (b). {\textcopyright} the Owner Societies.</p>
},
	doi = {10.1039/c0cp01882a},
	url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-79955530591\&doi=10.1039\%2fc0cp01882a\&partnerID=40\&md5=28fe652ac95f0c61e222f90d4f98f397},
	author = {Tsai, P.-Y. and Lin, K.-C.}
}
