@article {Tsai2013,
	title = {Note: Photodissociation of CH3COCN at 308 nm by time-resolved Fourier-transform infrared emission spectroscopy: Is CO a primary or secondary product?},
	journal = {Journal of Chemical Physics},
	volume = {138},
	number = {24},
	year = {2013},
	note = {<p>cited By 1</p>
},
	abstract = {<p>This Note aims to clarify the source of CO in photodissociation of acetyl cyanide (CH3COCN) at 308 nm. From the theoretical aspects, a new pathway via isomerization transition state (TS) at 391 {\textpm} 8 kJ/mol is found leading to the CO + CH3NC products. An amount of 60\% reactant molecules at 300 K is estimated to successfully surpass the average TS barrier lying above the excitation energy by 3.5 kJ/mol. Further, a prior distribution method is conducted to characterize the vibrational energy distribution of CO on a statistical basis. The pathway to CH3NC + CO yields a vibrational branching ratio (v = 0:v = 1:v = 2:v = 3\~{}0.63:0.25:0.093:0.032) in excellent agreement with the observation (0.62:0.25:0.09:0.05). {\textcopyright} 2013 AIP Publishing LLC.</p>
},
	keywords = {Branching ratio, carbon monoxide, Chemical reactions, Chemistry, cyanide, Cyanides, Emission spectroscopy, Fourier transform infra reds, Fourier Transform Infrared, infrared spectroscopy, letter, Photochemical Processes, PHOTOCHEMISTRY, Photodissociation, Prior distribution, Reactant molecules, Secondary product, SPECTROSCOPY, Theoretical aspects, TIME, Time Factors, Transition state, Vibrational energy distribution},
	doi = {10.1063/1.4812378},
	url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84879913792\&doi=10.1063\%2f1.4812378\&partnerID=40\&md5=bbc6634ce42a1501a43d1e43de04a145},
	author = {Tsai, P.-Y. and Lin, K.-C.}
}
