@article {Nakamura20165389,
	title = {Hexapole-Oriented Asymmetric-Top Molecules and Their Stereodirectional Photodissociation Dynamics},
	journal = {Journal of Physical Chemistry A},
	volume = {120},
	number = {27},
	year = {2016},
	note = {<p>cited By 11</p>
},
	pages = {5389-5398},
	abstract = {<p>Molecular orientation is a fundamental requisite in the study of stereodirected dynamics of collisional and photoinitiated processes. In this past decade, variable hexapolar electric filters have been developed and employed for the rotational-state selection and the alignment of molecules of increasing complexity, for which the main difficulties are their mass, their low symmetry, and the very dense rotational manifold. In this work, for the first time, a complex molecule such as 2-bromobutane, an asymmetric top containing a heavy atom (the bromine), was successfully oriented by a weak homogeneous field placed downstream from the hexapolar filter. Efficiency of the orientation was characterized experimentally, by combining time-of-flight measurements and a slice-ion-imaging detection technique. The application is described to the photodissociation dynamics of the oriented 2-bromobutane, which was carried out at a laser wavelength of 234 nm, corresponding to the breaking of the C-Br bond. The Br photofragment is produced in both the ground Br (2P3/2) and the excited Br (2P1/2) electronic states, and both channels are studied by the slice imaging technique, revealing new features in the velocity and angular distributions with respect to previous investigations on nonoriented molecules. {\textcopyright} 2016 American Chemical Society.</p>
},
	keywords = {Asymmetric top, Chemical reactions, Complex molecules, DYNAMICS, Homogeneous field, Imaging techniques, Laser wavelength, Molecular orientation, MOLECULES, Photodissociation, Photodissociation dynamics, Photofragments, Rotational state, Time of flight measurements},
	doi = {10.1021/acs.jpca.6b02410},
	url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84978719232\&doi=10.1021\%2facs.jpca.6b02410\&partnerID=40\&md5=e9f15294ac85a7040280995fd45132d5},
	author = {Nakamura, M. and Yang, S.-J. and Tsai, P.-Y. and Kasai, T. and Lin, K.-C. and Che, D.-C. and Lombardi, A. and Palazzetti, F. and Aquilanti, V.}
}
