Smallest carbon nanotube Is 3 angstrom in diameter

Citation:
Zhao, X., Liu Y., Inoue S., Suzuki T., Jones R. O., & Ando Y. (2004).  Smallest carbon nanotube Is 3 angstrom in diameter. Physical Review Letters. 92, 3., Mar, Number 12

Abstract:

Previous energetic considerations have led to the belief that carbon nanotubes (CNTs) of 4 Angstrom in diameter are the smallest stable CNTs. Using high-resolution transmission electron microscopy, we find that a stable 3 Angstrom CNT can be grown inside a multiwalled carbon nanotube. Density functional calculations indicate that the 3 Angstrom CNT is the armchair CNT(2,2) with a radial breathing mode at 787 cm(-1). Each end can be capped by half of a C(12) cage (hexagonal prism) containing tetragons.

Notes:

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