<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="6.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Muthusamy, Saravanakumar</style></author><author><style face="normal" font="default" size="100%">Sabhapathy, Palani</style></author><author><style face="normal" font="default" size="100%">Putikam Raghunath</style></author><author><style face="normal" font="default" size="100%">Sabbah, Amr</style></author><author><style face="normal" font="default" size="100%">Chang, Yu-Chung</style></author><author><style face="normal" font="default" size="100%">Krishnamoorthy, Vimal</style></author><author><style face="normal" font="default" size="100%">Ho, Thi-Thong</style></author><author><style face="normal" font="default" size="100%">Chiou, Jau-Wern</style></author><author><style face="normal" font="default" size="100%">Lin, Ming-Chang</style></author><author><style face="normal" font="default" size="100%">Li-Chyong Chen</style></author><author><style face="normal" font="default" size="100%">Kuei-Hsien Chen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Mimicking Metalloenzyme Microenvironments in the Transition Metal-Single Atom Catalysts for Electrochemical Hydrogen Peroxide Synthesis in an Acidic Medium</style></title><secondary-title><style face="normal" font="default" size="100%">Small Methods</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">d-band center</style></keyword><keyword><style  face="normal" font="default" size="100%">Electrocatalysis</style></keyword><keyword><style  face="normal" font="default" size="100%">electrochemical H2O2 production</style></keyword><keyword><style  face="normal" font="default" size="100%">electronic structures</style></keyword><keyword><style  face="normal" font="default" size="100%">oxygen reduction reaction</style></keyword><keyword><style  face="normal" font="default" size="100%">single-atom catalysts</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2023</style></year><pub-dates><date><style  face="normal" font="default" size="100%">2023</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">https://doi.org/10.1002/smtd.202300234</style></url></web-urls></urls><publisher><style face="normal" font="default" size="100%">John Wiley &amp; Sons, Ltd</style></publisher><pages><style face="normal" font="default" size="100%">2300234</style></pages><isbn><style face="normal" font="default" size="100%">2366-9608</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Abstract Electrochemical reduction of oxygen into hydrogen peroxide in an acidic medium offers an energy-efficient and green H2O2 synthesis as an alternative to the energy-intensive anthraquinone process. Unfortunately, high overpotential, low production rates, and fierce competition from traditional four-electron reduction limit it. In this study, a metalloenzyme-like active structure is mimicked in carbon-based single-atom electrocatalysts for oxygen reduction to H2O2. Using a carbonization strategy, the primary electronic structure of the metal center with nitrogen and oxygen coordination is modulated, followed by epoxy oxygen functionalities close to the metal active sites. In an acidic medium, CoNOC active structures proceed with greater than 98% H2O2 selectivity (2e?/2H+) rather than CoNC active sites that are selective to H2O (4e?/4H+). Among all MNOC (M = Fe, Co, Mn, and Ni) single-atom electrocatalysts, the CoNOC is the most selective (&amp;gt; 98%) for H2O2 production, with a mass activity of 10 A g?1 at 0.60 V vs. RHE. X-ray absorption spectroscopy is used to identify the formation of unsymmetrical MNOC active structures. Experimental results are also compared to density functional theory calculations, which revealed that the structure-activity relationship of the epoxy-surrounded CoNOC active structure reaches optimum (?G*OOH) binding energies for high selectivity.&lt;/p&gt;
</style></abstract><notes><style face="normal" font="default" size="100%">&lt;p&gt;&lt;a href=&quot;https://doi.org/10.1002/smtd.202300234&quot; rel=&quot;nofollow&quot;&gt;https://doi.org/10.1002/smtd.202300234&lt;/a&gt;&lt;/p&gt;
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