<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="6.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Tadesse Billo</style></author><author><style face="normal" font="default" size="100%">Fang-Yu Fu</style></author><author><style face="normal" font="default" size="100%">Putikam Raghunath</style></author><author><style face="normal" font="default" size="100%">Indrajit Shown</style></author><author><style face="normal" font="default" size="100%">Wei-Fu Chen</style></author><author><style face="normal" font="default" size="100%">Hsiang-Ting Lien</style></author><author><style face="normal" font="default" size="100%">Tzu-Hsien Shen</style></author><author><style face="normal" font="default" size="100%">Jyh-Fu Lee</style></author><author><style face="normal" font="default" size="100%">Ting-Shan Chan</style></author><author><style face="normal" font="default" size="100%">Kuo-You Huang</style></author><author><style face="normal" font="default" size="100%">Chih-I Wu</style></author><author><style face="normal" font="default" size="100%">M. C. Lin</style></author><author><style face="normal" font="default" size="100%">Jih-Shang Hwang</style></author><author><style face="normal" font="default" size="100%">Chih-Hao Lee</style></author><author><style face="normal" font="default" size="100%">Li-Chyong Chen</style></author><author><style face="normal" font="default" size="100%">Kuei-Hsien Chen</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Ni-Nanocluster Modified Black TiO2 with Dual Active Sites for Selective Photocatalytic CO2 Reduction</style></title><secondary-title><style face="normal" font="default" size="100%">Small</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">artificial photosynthesis</style></keyword><keyword><style  face="normal" font="default" size="100%">black TiO2</style></keyword><keyword><style  face="normal" font="default" size="100%">photocatalytic CO2 reduction</style></keyword><keyword><style  face="normal" font="default" size="100%">solar fuels</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2018</style></year></dates><urls><web-urls><url><style face="normal" font="default" size="100%">http://dx.doi.org/10.1002/smll.201702928</style></url></web-urls></urls><number><style face="normal" font="default" size="100%">2</style></number><volume><style face="normal" font="default" size="100%">14</style></volume><pages><style face="normal" font="default" size="100%">1702928–n/a</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;One of the key challenges in artificial photosynthesis is to design a photocatalyst that can bind and activate the CO2 molecule with the smallest possible activation energy and produce selective hydrocarbon products. In this contribution, a combined experimental and computational study on Ni-nanocluster loaded black TiO2 (Ni/TiO2[Vo]) with built-in dual active sites for selective photocatalytic CO2 conversion is reported. The findings reveal that the synergistic effects of deliberately induced Ni nanoclusters and oxygen vacancies provide (1) energetically stable CO2 binding sites with the lowest activation energy (0.08 eV), (2) highly reactive sites, (3) a fast electron transfer pathway, and (4) enhanced light harvesting by lowering the bandgap. The Ni/TiO2[Vo] photocatalyst has demonstrated highly selective and enhanced photocatalytic activity of more than 18 times higher solar fuel production than the commercial TiO2 (P-25). An insight into the mechanisms of interfacial charge transfer and product formation is explored.&lt;/p&gt;
</style></abstract><notes><style face="normal" font="default" size="100%">&lt;p&gt;1702928&lt;/p&gt;
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