@article {4598,
	title = {Constructing B-N-P Bonds in Ultrathin Holey g-C3N4 for Regulating the Local Chemical Environment in Photocatalytic CO2 Reduction to CO},
	journal = {Small},
	volume = {n/a},
	year = {2024},
	note = {<p>n/a</p>
},
	month = {2024},
	pages = {2400724},
	publisher = {John Wiley \& Sons, Ltd},
	abstract = {<p>Abstract The lack of intrinsic active sites for photocatalytic CO2 reduction reaction (CO2RR) and fast recombination rate of charge carriers are the main obstacles to achieving high photocatalytic activity. In this work, a novel phosphorus and boron binary-doped graphitic carbon nitride, highly porous material that exhibits powerful photocatalytic CO2 reduction activity, specifically toward selective CO generation, is disclosed. The coexistence of Lewis-acidic and Lewis-basic sites plays a key role in tuning the electronic structure, promoting charge distribution, extending light-harvesting ability, and promoting dissociation of excitons into active carriers. Porosity and dual dopants create local chemical environments that activate the pyridinic nitrogen atom between the phosphorus and boron atoms on the exposed surface, enabling it to function as an active site for CO2RR. The P?N?B triad is found to lower the activation barrier for reduction of CO2 by stabilizing the COOH reaction intermediate and altering the rate-determining step. As a result, CO yield increased to 22.45~{\textmu}mol~g?1~h?1 under visible light irradiation, which is ≈12 times larger than that of pristine graphitic carbon nitride. This study provides insights into the mechanism of charge carrier dynamics and active site determination, contributing to the understanding of the photocatalytic CO2RR mechanism.</p>
},
	keywords = {CO2 reduction, Exciton dissociation, Graphitic carbon nitride, metal-free, Photocatalysis, reaction mechanism},
	isbn = {1613-6810},
	url = {https://doi.org/10.1002/smll.202400724},
	author = {Kamal Hussien, Mahmoud and Sabbah, Amr and Mohammad Qorbani and Putikam, Raghunath and Kholimatussadiah, Septia and Tzou, Der-Lii M. and Hammad Elsayed, Mohamed and Lu, Yu-Jung and Wang, Yen-Yu and Lee, Xing-Hao and Lin, Tsai-Yu and Thang, Nguyen Quoc and Heng-Liang Wu and Haw, Shu-Chih and Wu, Kevin C.-W. and Lin, Ming-Chang and Kuei-Hsien Chen and Li-Chyong Chen}
}
